Beyond Perovskite Solar Cells: Tellurium Iodide as a Promising Light‐Absorbing Material for Solution‐Processed Photovoltaic Application

Searching new light‐absorbing materials to replace toxic lead halide in solar cells is very important and highly desirable. In this research, we firstly demonstrated that tellurium iodide (TeI₄) could be used as a light‐absorbing material in solar cells due to its suitable optical band gap and the active lone‐pair electron orbital in Te⁴⁺. The best power conversion efficiency (PCE=3.56%) was achieved with a concentration of 0.9 M TeI₄ in DMF:DMSO (4 : 1, v,v) without any heat treatment or antisolvent dripping. Our study indicates the promising potential of TeI₄ for photovoltaic and optoelectronic applications.     

考虑单元劈裂的流-固耦合连续-非连续方法及定向水力压裂模拟

为了更真实地模拟水力压裂过程中的岩石变形、裂缝扩展及流体流动,在自主开发的拉格朗日元与离散元耦合的连续-非连续方法的基础上,发展了一种流-固耦合方法。在该方法中,裂缝可沿四边形单元对角线和单元边界扩展,流体流动满足立方定律。通过与单一裂缝非稳态渗流模型及KGD模型的理论解进行对比,验证了该方法的正确性。由定向射孔水力压裂的模拟结果可以发现,(1)距离射孔越远,流体压力越小;随着时间的增加,裂缝中流体压力降低。(2)随着射孔角度的增加,裂缝起裂和扩展过程中的流体压力及转向距离增加;随着x方向水平应力的增加,裂缝起裂和扩展过程中的流体压力增加;两个方向水平应力之差越大,裂缝转向距离越小。(3)随着时间的增加,裂缝区段数目的增速变慢,这与裂缝体积增加变快有关。     

[100]LiF单晶在60 GPa以内冲击加载下的高压屈服强度特性

获取光学窗口自身的高压强度特性是开展材料高压高应变率冲击响应行为精密测量和数据反演的重要基础。利用平板撞击和双屈服面法,通过冲击-卸载、冲击-再加载原位粒子速度剖面精细测量和数据反演,获得了约60 GPa范围内[100]LiF屈服强度特性随冲击压力的变化规律。结果表明:在实验压力范围内,[100]LiF的屈服强度随加载压力的提高而显著提高,压力硬化效应显著;同时,LiF在冲击加载下的屈服强度高于磁驱准等熵加载结果,应变率硬化效应强于热软化效应。采用Huang-Asay模型确定了可描述冲击加载[100]LiF强度特性的本构模型参数,为LiF在强度、相变、层断裂等加窗测量实验中的深入应用和数据准确解读提供了重要支撑。     

一种弹体入水冲击波阴影成像可视化系统及其试验研究

扩大成像视野对于开展充水容器中弹体入水冲击波传播及弥散方面的可视化研究具有重要的实际意义。阴影成像技术适用于大视野实验,且对流场冲击波和扰动的可视化研究具有简单性和通用性,其中直接阴影成像最为简单,但可靠点光源的缺乏是阻碍其发展应用的瓶颈。因此基于国产短弧氙灯管,自制了短弧氙灯点光源,根据阴影成像原理,设计出一种弹体入水冲击波阴影成像可视化系统,详细介绍了其组成和运行原理。利用该系统对高速弹体入水进行了试验研究,获得了弹体入水冲击波的阴影成像和冲击波信号的压力时程曲线,通过阴影成像和冲击波信号相结合分析了弹体入水冲击波的传播特性,并进行了理论验证。结果表明:该弹体入水冲击波阴影成像可视化系统具有可靠性和设计的合理性。弹体高速入水后,初始冲击波的强度最大,随着冲击波的传播,冲击波强度逐渐降低,水中冲击波的传播速度不断降低,球形冲击波的半径逐渐增大。     

Constrained moving least‐squares immersed boundary method for fluid‐structure interaction analysis

A numerical method is presented for the analysis of interactions of inviscid and compressible flows with arbitrarily shaped stationary or moving rigid solids. The fluid equations are solved on a fixed rectangular Cartesian grid by using a higher‐order finite difference method based on the fifth‐order WENO scheme. A constrained moving least‐squares sharp interface method is proposed to enforce the Neumann‐type boundary conditions on the fluid‐solid interface by using a penalty term, while the Dirichlet boundary conditions are directly enforced. The solution of the fluid flow and the solid motion equations is advanced in time by staggerly using, respectively, the third‐order Runge‐Kutta and the implicit Newmark integration schemes. The stability and the robustness of the proposed method have been demonstrated by analyzing 5 challenging problems. For these problems, the numerical results have been found to agree well with their analytical and numerical solutions available in the literature. Effects of the support domain size and values assigned to the penalty parameter on the stability and the accuracy of the present method are also discussed.     

Chatter mitigation using the nonlinear tuned vibration absorber

A passive vibration absorber, termed the nonlinear tuned vibration absorber (NLTVA), is designed for the suppression of chatter vibrations. Unlike most passive vibration absorbers proposed in the literature for suppressing machine tool vibrations, the NLTVA comprises both a linear and a nonlinear restoring force. Its linear characteristics are tuned in order to optimize the stability properties of the machining operation, while its nonlinear properties are chosen in order to control the bifurcation behavior of the system and guarantee robustness of stable operation. In this study, the NLTVA is applied to turning machining.     

Diffusive-Dispersive Traveling Waves and Kinetic Relations: Part I: Nonconvex Hyperbolic Conservation Laws

Motivated by the theory of phase transition dynamics, we consider one-dimensional, nonlinear hyperbolic conservation laws with nonconvex flux-function containing vanishing nonlinear diffusive-dispersive terms. Searching for traveling wave solutions, we establish general results of existence, uniqueness, monotonicity, and asymptotic behavior. In particular, we investigate the properties of the traveling waves in the limits of dominant diffusion, dominant dispersion, and asymptotically small or large shock strength. As the diffusion and dispersion parameters tend to 0, the traveling waves converge to shock wave solutions of the conservation law, which either satisfy the classical Oleinik entropy criterion or are nonclassical undercompressive shocks violating it.     

高速扫描相机时间测量不确定度分析

以国内普遍使用的SJZ-30型高速扫描相机为例,用精测转速方法的结果处理数据,转速测量相对合成不确定度小于0.1%,时间间隔测量的相对扩展不确定度为0.2%.扫描速度在像面上的位置误差,采用"中值扫描速度",可予以校正.同时讨论了进一步降低转速测量不确定度和位置误差的方法.     

Gasdynamic characteristics of toroidal shock and detonation wave converging

Shock wave focusing is a fundamental problem in the shock wave research and the instantaneous impulse of high temperature and pressure generated at the focal points has been applied recently in industrial and medical researches[1]. There are several methods to create shock wave focusing, among which the more commonly-used one is to make a planar shock wave reflect from a concave surface, such as the elliptical or parabolic re- flector. Toroidal shock wave focusing has been proposed and investi…     

Riemann problem for kinematical conservation laws and geometrical features of nonlinear wavefronts

A pair of kinematical conservation laws (KCL) in a ray coordinatesystem (,t) are the basic equations governing the evolutionof a moving curve in two space dimensions. We first study elementarywave solutions and then the Riemann problem for KCL when themetric g, associated with the coordinate designating differentrays, is an arbitrary function of the velocity of propagationm of the moving curve. We assume that m>1 (m is appropriatelynormalized), for which the system of KCL becomes hyperbolic.We interpret the images of the elementary wave solutions inthe (,t)-plane to the (x,y)-plane as elementary shapes of themoving curve (or a nonlinear wavefront when interpreted in aphysical system) and then describe their geometrical properties.Solutions of the Riemann problem with different initial datagive the shapes of the nonlinear wavefront with different combinationsof elementary shapes. Finally, we study all possible interactionsof elementary shapes.